ID   1.14.11.81
DE   (-)-cyclopenine synthase.
CA   (1) (-)-cyclopeptine + 2-oxoglutarate + O2 = (Z)-dehydrocyclopeptine +
CA   CO2 + H2O + succinate.
CA   (2) (Z)-dehydrocyclopeptine + 2-oxoglutarate + O2 = (-)-cyclopenine +
CA   CO2 + succinate.
CC   -!- This fungal enzyme is involved in the biosynthesis of quinolone
CC       compounds.
CC   -!- it catalyzes two oxidation reactions: the first reaction results in a
CC       desaturation; the second reaction is a monooxygenation of the double
CC       bond, forming an epoxide.
CC   -!- The enzyme is also active with 4'-methoxycyclopeptine.
DR   Q5AR53, ASQJ_EMENI ;
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