ID   1.14.13.22
DE   Cyclohexanone monooxygenase.
AN   Cyclohexanone 1,2-monooxygenase.
AN   Cyclohexanone oxygenase.
AN   Cyclohexanone:NADPH:oxygen oxidoreductase (6-hydroxylating, 1,2-
AN   lactonizing).
CA   Cyclohexanone + NADPH + O(2) = hexano-6-lactone + NADP(+) + H(2)O.
CF   FAD.
CC   -!- In the catalytic mechanism of this enzyme, the nucleophilic species
CC       that attacks the carbonyl group is a peroxyflavin intermediate that
CC       is generated by reaction of the enzyme-bound flavin cofactor with
CC       NAD(P)H and oxygen.
CC   -!- This enzyme is able to catalyze a wide range of oxidative reactions,
CC       including enantioselective Baeyer-Villiger reactions, sulfoxidations,
CC       amine oxidations and epoxidations.
DR   P12015, CYMO_ACISP ;
//