ID 1.14.19.43 DE palmitoyl-[glycerolipid] 3-(E)-desaturase. CA a 1-acyl-2-hexadecanoyl-glycerolipid + 2 H(+) + O2 + 2 reduced [2Fe-2S]- CA [ferredoxin] = a 1-acyl-2-[(3E)-hexadec-3-enoyl]-glycerolipid + 2 H2O + CA 2 oxidized [2Fe-2S]-[ferredoxin]. CC -!- The enzyme introduces an unusual trans double bond at carbon 3 of a CC palmitoyl group attached to the sn-2 position of glycerolipids. CC -!- The enzyme from the plant Arabidopsis thaliana is specific for CC palmitate in phosphatidylglycerol. CC -!- The enzyme from tobacco can also accept oleate and alpha-linolenate CC if present at the sn-2 position of phosphatidylglycerol. DR Q9SZ42, FAD4_ARATH ; //