ID 1.14.19.79 DE 3beta,22alpha-dihydroxysteroid 3-dehydrogenase. AN CYP90A1. CA (1) (22S)-22-hydroxycampesterol + O2 + reduced [NADPH--hemoprotein CA reductase] = (22S)-22-hydroxycampest-4-en-3-one + H(+) + 2 H2O + oxidized CA [NADPH--hemoprotein reductase]. CA (2) 6-deoxoteasterone + O2 + reduced [NADPH--hemoprotein reductase] = CA 3-dehydro-6-deoxoteasterone + H(+) + 2 H2O + oxidized [NADPH--hemoprotein CA reductase]. CC -!- This cytochrome P450 (heme-thiolate) enzyme, characterized from the CC plant Arabidopsis thaliana, catalyzes C-3 dehydrogenation of all CC 3beta-hydroxy brassinosteroid synthesis intermediates with CC 22-hydroxylated or 2(2),2(3)-dihydroxylated side chains. DR Q42569, C90A1_ARATH; I1IUJ6, C90A1_BRADI; //