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ENZYME entry: EC 1.14.20.2

Accepted Name
2,4-dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase.
Alternative Name(s)
DIBOA-Glc dioxygenase.
Reaction catalysed
(2R)-4-hydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside + 2-oxoglutarate + O(2) <=> (2R)-4,7-dihydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside + succinate + CO(2) + H(2)O
Comment(s)
The enzyme is involved in the biosynthesis of protective and allelophatic benzoxazinoids in some plants, most commonly from the family of Poacea (grasses).
Cross-references
BRENDA1.14.20.2
EC2PDB1.14.20.2
ExplorEnz1.14.20.2
PRIAM enzyme-specific profiles1.14.20.2
KEGG Ligand Database for Enzyme Nomenclature1.14.20.2
IUBMB Enzyme Nomenclature1.14.20.2
IntEnz1.14.20.2
MEDLINEFind literature relating to 1.14.20.2
MetaCyc1.14.20.2
UniProtKB/Swiss-Prot
Q84TC2, BX6_MAIZE

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