ENZYME entry: EC 1.14.21.1
| Accepted Name |
| (S)-stylopine synthase.
|
| Alternative Name(s) |
| (S)-cheilanthifoline oxidase (methylenedioxy-bridge-forming). |
| Reaction catalysed |
| (S)-cheilanthifoline + NADPH + O(2) <=> (S)-stylopine + NADP(+) + 2 H(2)O |
| Cofactor(s) |
| Heme-thiolate.
|
| Comment(s) |
- Catalyzes an oxidative reaction that does not incorporate oxygen into
the product.
- Forms the second methylenedioxy bridge of the protoberberine alkaloid
stylopine from oxidative ring closure of adjacent phenolic and
methoxy groups of cheilanthifoline.
- Formerly EC 1.1.3.32.
|
| Cross-references |
| BRENDA | 1.14.21.1 |
| EC2PDB | 1.14.21.1 |
| ExplorEnz | 1.14.21.1 |
| PRIAM enzyme-specific profiles | 1.14.21.1 |
| KEGG Ligand Database for Enzyme Nomenclature | 1.14.21.1 |
| IUBMB Enzyme Nomenclature | 1.14.21.1 |
| IntEnz | 1.14.21.1 |
| MEDLINE | Find literature relating to 1.14.21.1 |
| MetaCyc | 1.14.21.1 |
| UniProtKB/Swiss-Prot |
|
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