ID 1.3.1.81 DE (+)-pulegone reductase. CA (1) (-)-menthone + NADP(+) = (+)-pulegone + NADPH. CA (2) (+)-isomenthone + NADP(+) = (+)-pulegone + NADPH. CC -!- NADH cannot replace NADPH as reductant. CC -!- The Delta(8,9)-double bond of (+)-cis-isopulegone and the Delta(1,2)- CC double bond of (+-)-piperitone are not substrates. CC -!- The enzyme from peppermint (Mentha x piperita) converts (+)-pulegone CC into both (-)-menthone and (+)-isomenthone at a ratio of 70:30 for CC native enzyme but it does not catalyze the reverse reaction. DR Q6WAU0, PULR_MENPI ; //