ID 1.8.2.2 DE thiosulfate dehydrogenase. AN tetrathionate synthase. CA 2 Fe(III)-[cytochrome c] + 2 thiosulfate = 2 Fe(II)-[cytochrome c] + CA 2 H(+) + tetrathionate. CC -!- The enzyme catalyzes the reversible formation of a sulfur-sulfur bond CC between the sulfane atoms of two thiosulfate molecules, yielding CC tetrathionate and releasing two electrons. CC -!- In many bacterial species the enzyme is a diheme c-type cytochrome. CC -!- In a number of organisms, including Thiomonas intermedia and CC Sideroxydans lithotrophicus, a second diheme cytochrome (TsdB) acts CC as the electron acceptor. CC -!- However, some organisms, such as Allochromatium vinosum, lack TsdB. CC -!- The electron acceptor in these organisms may be the high-potential CC iron-sulfur protein (HiPIP). DR D3RVD4, TSDA_ALLVD ; Q4FQB7, TSDA_PSYA2 ; A4VND8, TSDA_STUS1 ; DR D5WYQ5, TSDA_THIK1 ; //