ID   2.3.1.169
DE   CO-methylating acetyl-CoA synthase.
AN   ACS.
CA   Acetyl-CoA + corrinoid protein = CO + methylcorrinoid protein + CoA.
CF   Iron-sulfur; Nickel.
CC   -!- Also catalyzes exchange reactions of carbon between C-1 of acetyl-CoA
CC       and CO, and between C-2 of acetyl-CoA and methyl corrinoid protein.
CC   -!- Involved, together with EC 1.2.7.4, in the synthesis of acetyl-CoA
CC       from CO(2) and H(2).
CC   -!- To follow its stoichiometry, the reaction can be written as: CH(3)-
CC       CO-S-CoA + protein Co(+) + H(+) = CO + protein Co(2+)-CH(3) + HS-CoA.
DR   P27988, DCMA_MOOTH ;
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