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ENZYME entry: EC

Accepted Name
3,5,7-trioxododecanoyl-CoA synthase.
Alternative Name(s)
Olivetol synthase.
Reaction catalysed
3 malonyl-CoA + hexanoyl-CoA <=> 3 CoA + 3,5,7-trioxododecanoyl-CoA + 3 CO(2)
  • A polyketide synthase catalyzing the first committed step in the cannabinoids biosynthetic pathway of the plant Cannabis sativa.
  • The enzyme was previously thought to also function as a cyclase, but the cyclization is now known to be catalyzed by EC
PRIAM enzyme-specific profiles2.3.1.206
KEGG Ligand Database for Enzyme Nomenclature2.3.1.206
IUBMB Enzyme Nomenclature2.3.1.206
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