ID 2.3.2.35 DE capsaicin synthase. CA (6E)-8-methylnon-6-enoyl-CoA + vanillylamine = capsaicin + CoA + H(+). CC -!- The enzyme, found only in plants that belong to the Capsicum genus, CC catalyzes the last step in the biosynthesis of capsaicinoids. CC -!- The enzyme catalyzes the acylation of vanillylamine by a branched- CC chain fatty acid. CC -!- The exact structure of the fatty acid determines the type of CC capsaicinoid formed. DR D2Y3X2, PUN1_CAPAN ; A0A2G3D6U1, PUN1_CAPCH ; Q58VT1, PUN1_CAPFR ; //