ID 2.4.1.217 DE mannosyl-3-phosphoglycerate synthase. AN MPG synthase. CA (2R)-3-phosphoglycerate + GDP-alpha-D-mannose = 2-O-(alpha-D-mannosyl)-3- CA phosphoglycerate + GDP + H(+). CC -!- The enzyme is absolutely specific for GDP-mannose and CC 3-phosphoglycerate, and transfers the mannosyl group with retention CC of configuration. CC -!- In the hyperthermophilic archaeon Pyrococcus horikoshii, CC the mannosyl-3-phosphoglycerate formed is subsequently CC dephosphorylated by a specific phosphatase, EC 3.1.3.70, producing CC mannosylglycerate. DR Q9YDM5, MPGS_AERPE ; Q9UZC1, MPGS_PYRAB ; Q8U380, MPGS_PYRFU ; DR O58689, MPGS_PYRHO ; //