ID 2.4.1.241 DE digalactosyldiacylglycerol synthase. AN DGDG synthase. AN UDP-galactose:MGDG galactosyltransferase. AN UDP-galactose-dependent DGDG synthase. AN UDP-galactose-dependent digalactosyldiacylglycerol synthase. CA a 1,2-diacyl-3-O-(beta-D-galactosyl)-sn-glycerol + UDP-alpha-D-galactose CA = 1,2-diacyl-3-O-[alpha-D-galactosyl-(1->6)-beta-D-galactosyl]- CA sn-glycerol + H(+) + UDP. CC -!- Diacylglycerol cannot serve as an acceptor molecule for CC galactosylation as in the reaction catalyzed by EC 2.4.1.46. CC -!- When phosphate is limiting, phospholipids in plant membranes are CC reduced but these are replaced, at least in part, by the glycolipids CC digalactosyldiacylglycerol (DGDG) and sulfoquinovosyldiacylglycerol. CC -!- While both DGD1 and DGD2 are increased under phosphate-limiting CC conditions, DGD2 does not contribute significantly under optimal CC growth conditions. CC -!- DGD2 is responsible for the synthesis of DGDG molecular species that CC are rich in C16 fatty acids at sn-1 of diacylglycerol whereas DGD1 CC leads to molecular species rich in C18 fatty acids. CC -!- The enzyme has been localized to the outer side of chloroplast CC envelope membranes. DR Q9S7D1, DGDG1_ARATH; Q6DW74, DGDG1_LOTJA; Q6DW76, DGDG1_SOYBN; DR Q8W1S1, DGDG2_ARATH; Q6DW73, DGDG2_LOTJA; Q6DW75, DGDG2_SOYBN; //