ID 2.4.1.246 DE mannosylfructose-phosphate synthase. AN mannosylfructose-6-phosphate synthase. AN MFPS. CA beta-D-fructose 6-phosphate + GDP-alpha-D-mannose = beta-D- CA fructofuranosyl alpha-D-mannopyranoside 6(F)-phosphate + GDP + H(+). CC -!- GDP-mannose can be replaced by ADP-mannose but with a concomitant CC decrease in activity. CC -!- The product of this reaction is dephosphorylated by EC 3.1.3.79 to CC form the non-reducing disaccharide mannosylfructose, which is the CC major endogenous osmolyte produced by several alpha-proteobacteria in CC response to osmotic stress. CC -!- The F in the product name is used to indicate that the fructose CC residue of sucrose carries the substituent. DR A7TZT2, MFPS_AGRFC ; //