ID 3.1.1.100 DE chlorophyllide a hydrolase. AN bciC (gene name). CA chlorophyllide a + H(+) + H2O = 8-ethyl-12-methyl-3- CA vinylbacteriochlorophyllide d + CO2 + methanol. CC -!- This enzyme, found in green sulfur bacteria (Chlorobiaceae) and green CC filamentous bacteria (Chloroflexaceae), catalyzes the first committed CC step in the biosynthesis of bacteriochlorophylls c, d and e, CC the removal of the C-13(2)-methylcarboxyl group from chlorophyllide CC a. CC -!- The reaction is very similar to the conversion of pheophorbide a to CC pyropheophorbide a during chlorophyll a degradation, which is CC catalyzed by EC 3.1.1.82. //