ENZYME entry: EC 3.1.1.78
| Accepted Name |
|---|
| Polyneuridine-aldehyde esterase.
|
| Alternative Name(s) |
|---|
| PNAE. |
| Polyneuridine aldehyde esterase. |
| Reaction catalysed |
|---|
| Polyneuridine aldehyde + H(2)O <=> 16-epivellosimine + CO(2) + methanol |
| Comment(s) |
|---|
- Following hydrolysis of this indole alkaloid ester, the carboxylic
acid decarboxylates spontaneously giving the sarpagan skeleton.
- Also acts on akuammidine aldehyde (the 16-epimer of polyneuridine
aldehyde).
|
| Cross-references |
|---|
| BRENDA | 3.1.1.78 |
| EC2PDB | 3.1.1.78 |
| ExplorEnz | 3.1.1.78 |
| PRIAM enzyme-specific profiles | 3.1.1.78 |
| KEGG Ligand Database for Enzyme Nomenclature | 3.1.1.78 |
| IUBMB Enzyme Nomenclature | 3.1.1.78 |
| IntEnz | 3.1.1.78 |
| MEDLINE | Find literature relating to 3.1.1.78 |
| MetaCyc | 3.1.1.78 |
| UniProtKB/Swiss-Prot |
|
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