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ENZYME entry: EC 3.7.1.18

Accepted Name
6-oxocamphor hydrolase.
Reaction catalysed
Bornane-2,6-dione + H(2)O <=> ((1S)-4-hydroxy-2,2,3-trimethylcyclopent-3-enyl)acetate
Comment(s)
  • Isolated from Rhodococcus sp.
  • The bornane ring system is cleaved by a retro-Claisen reaction to give the enol of alpha-campholonate.
  • When separate from the enzyme the enol is tautomerised to the keto form as a 6:1 mixture of ((1S,3R)-2,2,3-trimethyl-4- oxocyclopentyl)acetate and ((1S,3S)-2,2,3-trimethyl-4- oxocyclopentyl)acetate.
Cross-references
BRENDA3.7.1.18
EC2PDB3.7.1.18
ExplorEnz3.7.1.18
PRIAM enzyme-specific profiles3.7.1.18
KEGG Ligand Database for Enzyme Nomenclature3.7.1.18
IUBMB Enzyme Nomenclature3.7.1.18
IntEnz3.7.1.18
MEDLINEFind literature relating to 3.7.1.18
MetaCyc3.7.1.18
UniProtKB/Swiss-Prot
Q93TU6, CAMK_RHOSO

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All UniProtKB/Swiss-Prot entries referenced in this entry, with possibility to download in different formats, align etc.
All ENZYME / UniProtKB/Swiss-Prot entries corresponding to 3.7.1.-
All ENZYME / UniProtKB/Swiss-Prot entries corresponding to 3.7.-.-
All ENZYME / UniProtKB/Swiss-Prot entries corresponding to 3.-.-.-