ID 4.1.1.72 DE Branched-chain-2-oxoacid decarboxylase. AN (3S)-3-methyl-2-oxopentanoate carboxy-lyase. CA (3S)-3-methyl-2-oxopentanoate = 2-methylbutanal + CO(2). CC -!- Acts on a number of 2-oxo acids, with a high affinity toward CC branched-chain substrates. CC -!- The aldehyde formed may be enzyme-bound, and may be an intermediate CC in the bacterial system for biosynthesis of branched-chain fatty CC acids. //