ID   4.2.1.92
DE   Hydroperoxide dehydratase.
AN   Allene oxide synthase.
AN   AOS.
AN   Hydroperoxide isomerase.
CA   (9Z,11E,15Z)-(13S)-hydroperoxyoctadeca-9,11,15-trienoate = (9Z,15Z)-
CA   (13S)-12,13-epoxyoctadeca-9,11,15-trienoate + H(2)O.
CF   Heme-thiolate.
CC   -!- Acts on a number of unsaturated fatty-acid hydroperoxides, forming
CC       the corresponding allene oxides.
CC   -!- The product of the above reaction is unstable and is acted upon by
CC       EC 5.3.99.6 to form the cyclopentenone derivative (15Z)-12-oxophyto-
CC       10,15-dienoate (OPDA), which is the first cyclic and biologically
CC       active metabolite in the jasmonate biosynthesis pathway.
PR   PROSITE; PDOC00081;
DR   O16025, AOSL_PLEHO ;  Q7Y0C8, C74A1_ORYSJ;  Q7XYS3, C74A2_ORYSJ;
DR   Q40778, C74A2_PARAR;  Q6Z6L1, C74A3_ORYSJ;  Q6Z6K9, C74A4_ORYSJ;
DR   Q96242, CP74A_ARATH;  P48417, CP74_LINUS ;
//