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ENZYME entry: EC 184.108.40.206
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|(-)-endo-alpha-bergamotene synthase ((2Z,6Z)-farnesyl diphosphate
|(2Z,6Z)-farnesyl diphosphate <=> (-)-endo-alpha-bergamotene|
- The enzyme synthesizes a mixture of sesquiterpenoids from (2Z,6Z)-
- Following dephosphorylation of (2Z,6Z)-farnesyl diphosphate,
the (2Z,6Z)-farnesyl carbocation is converted to either the (6R)- or
the (6S)-bisabolyl cations depending on the stereochemistry of the
- The (6R)-bisabolyl cation will then lead to the formation of (+)-
alpha-santalene (see EC 220.127.116.11), while the (6S)-bisabolyl cation
will give rise to (+)-endo-beta-bergamotene (EC 18.104.22.168) as well as
- Small amounts of (-)-epi-beta-santalene are also formed from the
(6R)-bisabolyl cation and small amounts of (-)-exo-alpha-bergamotene
are formed from the (6S)-bisabolyl cation (1).
|PRIAM enzyme-specific profiles||22.214.171.124|
|KEGG Ligand Database for Enzyme Nomenclature||126.96.36.199|
|IUBMB Enzyme Nomenclature||188.8.131.52|
|MEDLINE||Find literature relating to 184.108.40.206|
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entries corresponding to 4.2.3.-
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