ID 5.3.2.6 DE 2-hydroxymuconate tautomerase. AN 4-oxalocrotonate isomerase. AN 4-oxalocrotonate tautomerase. CA (2Z,4E)-2-hydroxyhexa-2,4-dienedioate = (3E)-2-oxohex-3-enedioate. CC -!- Involved in the meta-cleavage pathway for the degradation of phenols, CC modified phenols and catechols. CC -!- The enol form (2Z,4E)-2-hydroxyhexa-2,4-dienedioate is produced as CC part of this pathway and is converted to the keto form (3E)-2-oxohex- CC 3-enedioate by the enzyme. CC -!- Another keto form, (4E)-2-oxohex-4-enedioate (4-oxalocrotonate), CC was originally thought to be produced by the enzyme but later shown CC to be produced non-enzymatically. DR Q01468, 4OT1_PSEPU ; Q8RQD2, 4OT2_PSEPU ; Q9Z431, 4OT3_PSEPU ; DR Q93JW0, 4OT4_PSEPU ; P70994, 4OT_BACSU ; Q9RHM8, 4OT_COMTE ; DR Q8KRR5, 4OT_PSEFL ; P49172, 4OT_PSEUF ; Q9ZI54, 4OT_STUST ; //