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ENZYME

ENZYME entry: EC 5.5.1.15

Accepted Name
terpentedienyl-diphosphate synthase
Alternative Name(s)
clerodadienyl diphosphate synthase
terpentedienol diphosphate synthase
Reaction catalysed
(2E,6E,10E)-geranylgeranyl diphosphate <=> terpentedienyl diphosphate
Comment(s)
  • Contains a DXDD motif, which is a characteristic of diterpene cylases whose reactions are initiated by protonation at the 14,15-double bond of geranylgeranyl diphosphate (GGDP).
  • The triggering proton is lost at the end of the cyclization reaction.
  • The product of the reaction, terpentedienyl diphosphate, is the substrate for EC 4.2.3.36 and is a precursor of the diterpenoid antibiotic terpentecin.
Cross-references
BRENDA5.5.1.15
EC2PDB5.5.1.15
ExplorEnz5.5.1.15
PRIAM enzyme-specific profiles5.5.1.15
KEGG Ligand Database for Enzyme Nomenclature5.5.1.15
IUBMB Enzyme Nomenclature5.5.1.15
IntEnz5.5.1.15
MEDLINEFind literature relating to 5.5.1.15
MetaCyc5.5.1.15
Rhea expert-curated reactions5.5.1.15
UniProtKB/Swiss-Prot
Q9AJE4, CYC1_KITGR

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