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ENZYME

ENZYME entry: EC 1.1.1.187

Accepted Name
GDP-4-dehydro-D-rhamnose reductase
Alternative Name(s)
GDP-4-keto-6-deoxy-D-mannose reductase
GDP-4-keto-D-rhamnose reductase
guanosine diphosphate-4-keto-D-rhamnose reductase
Reaction catalysed
  • GDP-alpha-D-rhamnose + NAD(+) = GDP-4-dehydro-alpha-D-rhamnose + H(+) + NADH
  • GDP-alpha-D-rhamnose + NADP(+) = GDP-4-dehydro-alpha-D-rhamnose + H(+) + NADPH
  • GDP-6-deoxy-alpha-D-talose + NADP(+) = GDP-4-dehydro-alpha-D-rhamnose + H(+) + NADPH
  • GDP-6-deoxy-alpha-D-talose + NAD(+) = GDP-4-dehydro-alpha-D-rhamnose + H(+) + NADH
Comment(s)
The enzyme, which operates in the opposite direction to that shown, forms a mixture of GDP-alpha-D-rhamnose and its C-4 epimer, GDP-6- deoxy-alpha-D-talose. cf. EC 1.1.1.135 and EC 1.1.1.281.
Cross-references
BRENDA1.1.1.187
EC2PDB1.1.1.187
ExplorEnz1.1.1.187
PRIAM enzyme-specific profiles1.1.1.187
KEGG Ligand Database for Enzyme Nomenclature1.1.1.187
IUBMB Enzyme Nomenclature1.1.1.187
IntEnz1.1.1.187
MEDLINEFind literature relating to 1.1.1.187
MetaCyc1.1.1.187
Rhea expert-curated reactions1.1.1.187

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