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ENZYME entry: EC 1.1.1.353

Accepted Name
versiconal hemiacetal acetate reductase.
Alternative Name(s)
VHA reductase.
Reaction catalysed
  • (2S)-versicolorone + NADP(+) <=> 1'-hydroxyversicolorone + H(+) + NADPH
  • (3S)-versiconol acetate + NADP(+) <=> (2S,3S)-versiconal hemiacetal acetate + H(+) + NADPH
  • (S)-versiconol + NADP(+) <=> (2S-3S)-versiconal hemiacetal + H(+) + NADPH
Comment(s)
  • Isolated from the mold Aspergillus parasiticus.
  • Involved in a metabolic grid that leads to aflatoxin biosynthesis.
Cross-references
BRENDA1.1.1.353
EC2PDB1.1.1.353
ExplorEnz1.1.1.353
PRIAM enzyme-specific profiles1.1.1.353
KEGG Ligand Database for Enzyme Nomenclature1.1.1.353
IUBMB Enzyme Nomenclature1.1.1.353
IntEnz1.1.1.353
MEDLINEFind literature relating to 1.1.1.353
MetaCyc1.1.1.353
Rhea expert-curated reactions1.1.1.353
UniProtKB/Swiss-Prot
B9WYE6, VRDA_ASPPA

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