ID   1.11.1.19
DE   dye decolorizing peroxidase.
AN   DyP.
AN   DyP-type peroxidase.
CA   2 H2O2 + Reactive Blue 5 = 2,2'-disulfonyl azobenzene + 3-[(4-amino-6-
CA   chloro-1,3,5-triazin-2-yl)amino]benzenesulfonate + 2 H(+) + 2 H2O +
CA   phthalate.
CC   -!- Heme proteins with proximal histidine secreted by basidiomycetous
CC       fungi and eubacteria.
CC   -!- They are similar to EC 1.11.1.16 versatile peroxidase (oxidation of
CC       Reactive Black 5, phenols, veratryl alcohol), but differ from the
CC       latter in their ability to efficiently oxidize a number of
CC       recalcitrant anthraquinone dyes, and inability to oxidize Mn(II).
CC   -!- The model substrate Reactive Blue 5 is converted with high efficiency
CC       via a so far unique mechanism that combines oxidative and hydrolytic
CC       steps and leads to the formation of phthalic acid.
CC   -!- Bacterial TfuDyP catalyzes sulfoxidation.
DR   K7N5M8, DYP2_AMYS7 ;  I2DBY1, DYP_AURAJ  ;  I2DBY2, DYP_EXIGL  ;
DR   I2DBY3, DYP_MYCEP  ;  Q47KB1, DYP_THEFY  ;  B0BK71, MSP1_MYCSO ;
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