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ENZYME entry: EC 1.13.11.72

Accepted Name
2-hydroxyethylphosphonate dioxygenase.
Alternative Name(s)
HEPD.
Reaction catalysed
2-hydroxyethylphosphonate + O2 <=> formate + H(+) + hydroxymethylphosphonate
Comment(s)
  • Isolated from some bacteria including Streptomyces hygroscopicus and Streptomyces viridochromogenes.
  • The pro-R hydrogen at C-2 of the ethyl group is retained by the formate ion.
  • Any stereochemistry at C-1 of the ethyl group is lost.
  • One atom from dioxygen is present in each product.
  • Involved in phosphinothricin biosynthesis.
Cross-references
BRENDA1.13.11.72
EC2PDB1.13.11.72
ExplorEnz1.13.11.72
PRIAM enzyme-specific profiles1.13.11.72
KEGG Ligand Database for Enzyme Nomenclature1.13.11.72
IUBMB Enzyme Nomenclature1.13.11.72
IntEnz1.13.11.72
MEDLINEFind literature relating to 1.13.11.72
MetaCyc1.13.11.72
Rhea expert-curated reactions1.13.11.72
UniProtKB/Swiss-Prot
Q5IW40, HEPD_STRVT

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