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ENZYME

ENZYME entry: EC 1.13.11.92

PURL: https://purl.expasy.org/enzyme/EC/1.13.11.92
Accepted Name
fatty acid alpha-dioxygenase
Reaction catalysed
a 1,2-saturated fatty acid + O2 = a (2R)-2-hydroperoxy fatty acid
Comment(s)
  • Contains heme.
  • This plant enzyme catalyzes the (2R)-hydroperoxidation of fatty acids.
  • It differs from lipoxygenases and cyclooxygenases in that the oxygen addition does not target an unsaturated region in the fatty acid.
  • In vitro the product undergoes spontaneous decarboxylation, resulting in formation of a chain-shortened aldehyde.
  • In vivo the product may be reduced to a (2R)-2-hydroxyfatty acid.
  • The enzyme, which is involved in responses to different abiotic and biotic stresses, has a wide substrate range that includes both saturated and unsaturated fatty acids.
Cross-references
BRENDA1.13.11.92
EC2PDB1.13.11.92
ExplorEnz1.13.11.92
KEGG Ligand Database for Enzyme Nomenclature1.13.11.92
IUBMB Enzyme Nomenclature1.13.11.92
MEDLINEFind literature relating to 1.13.11.92
MetaCyc1.13.11.92
Rhea expert-curated reactions1.13.11.92
UniProtKB/Swiss-Prot
Q9SGH6, DOX1_ARATHQ2QRV3, PIOX_ORYSJQ5GQ66, PIOX_PEA
A0A1S3ZX38, PIOX_TOBAC

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