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ENZYME

ENZYME entry: EC 1.14.11.43

PURL: https://purl.expasy.org/enzyme/EC/1.14.11.43
Accepted Name
(S)-dichlorprop dioxygenase (2-oxoglutarate)
Alternative Name(s)
(S)-mecoprop dioxygenase
(S)-phenoxypropionate/alpha-ketoglutarate-dioxygenase
2-oxoglutarate-dependent (S)-dichlorprop dioxygenase
2-oxoglutarate-dependent (S)-mecoprop dioxygenase
alpha-ketoglutarate-dependent (S)-dichlorprop dioxygenase
Reaction catalysed
  • (S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2 = 2-methyl-4-chlorophenol + pyruvate + succinate + CO2
  • (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 = 2,4-dichlorophenol + pyruvate + succinate + CO2
Comment(s)
The enzymes from the Gram-negative bacteria Delftia acidovorans MC1 and Sphingomonas herbicidovorans MH are involved in the degradation of the (S)-enantiomer of the phenoxyalkanoic acid herbicides mecoprop and dichlorprop.
Cross-references
BRENDA1.14.11.43
EC2PDB1.14.11.43
ExplorEnz1.14.11.43
KEGG Ligand Database for Enzyme Nomenclature1.14.11.43
IUBMB Enzyme Nomenclature1.14.11.43
MEDLINEFind literature relating to 1.14.11.43
MetaCyc1.14.11.43
Rhea expert-curated reactions1.14.11.43
UniProtKB/Swiss-Prot
P83309, SDPA_DELACQ700X4, SDPA_SPHHM

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