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ENZYME entry: EC 1.14.13.107

Accepted Name
limonene 1,2-monooxygenase.
Reaction catalysed
  • (4S)-limonene + H(+) + NADPH + O2 <=> H2O + limonene 1,2-epoxide + NADP(+)
  • (4S)-limonene + H(+) + NADH + O2 <=> H2O + limonene 1,2-epoxide + NAD(+)
  • (4R)-limonene + H(+) + NADH + O2 <=> H2O + limonene 1,2-epoxide + NAD(+)
  • (4R)-limonene + H(+) + NADPH + O2 <=> H2O + limonene 1,2-epoxide + NADP(+)
Comment(s)
  • Limonene is the most widespread terpene and is formed by more than 300 plants.
  • Rhodococcus erythropolis DCL14, a Gram-positive bacterium, is able to grow on both (S)-limonene and (R)-limonene as the sole source of carbon and energy.
  • NADPH can act instead of NADH, although more slowly.
  • It has not been established if the product formed is optically pure or a mixture of two enantiomers.
Cross-references
BRENDA1.14.13.107
EC2PDB1.14.13.107
ExplorEnz1.14.13.107
PRIAM enzyme-specific profiles1.14.13.107
KEGG Ligand Database for Enzyme Nomenclature1.14.13.107
IUBMB Enzyme Nomenclature1.14.13.107
IntEnz1.14.13.107
MEDLINEFind literature relating to 1.14.13.107
MetaCyc1.14.13.107
Rhea expert-curated reactions1.14.13.107
UniProtKB/Swiss-Prot
Q9EUT9, LIMB_RHOER

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