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ENZYME entry: EC 1.14.13.208

Accepted Name
Benzoyl-CoA 2,3-epoxidase.
Alternative Name(s)
Benzoyl-CoA 2,3-dioxygenase.
Benzoyl-CoA dioxygenase/reductase.
Reaction catalysed
Benzoyl-CoA + NADPH + O(2) <=> 2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP(+) + H(2)O
Cofactor(s)
FAD; Fe cation; Iron-sulfur.
Comment(s)
  • The enzyme is involved in aerobic benzoate metabolism in Azoarcus evansii.
  • BoxB functions as the oxygenase part of benzoyl-CoA oxygenase in conjunction with BoxA, the reductase component, which upon binding of benzoyl-CoA, transfers two electrons to the ring in the course of dioxygenation.
  • Formerly EC 1.14.12.21 and EC 1.14.12.n1.
Cross-references
BRENDA1.14.13.208
EC2PDB1.14.13.208
ExplorEnz1.14.13.208
PRIAM enzyme-specific profiles1.14.13.208
KEGG Ligand Database for Enzyme Nomenclature1.14.13.208
IUBMB Enzyme Nomenclature1.14.13.208
IntEnz1.14.13.208
MEDLINEFind literature relating to 1.14.13.208
MetaCyc1.14.13.208
Rhea expert-curated reactions1.14.13.208
UniProtKB/Swiss-Prot
Q9AIX6, BOXA_AROEV;  Q9AIX7, BOXB_AROEV;  

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