ID 1.14.13.212 DE 1,3,7-trimethyluric acid 5-monooxygenase. CA 1,3,7-trimethylurate + NADH + O2 + H(+) = 1,3,7-trimethyl-5- CA hydroxyisourate + NAD(+) + H2O. CC -!- The enzyme, characterized from the bacterium Pseudomonas sp. CBB1, CC is part of the bacterial C-8 oxidation-based caffeine degradation CC pathway. CC -!- The product decomposes spontaneously to a racemic mixture of 3,6,8- CC trimethylallantoin. CC -!- The enzyme shows no acitivity with urate. cf. EC 1.14.13.113. //