ID   1.14.13.216
DE   asperlicin C monooxygenase.
CA   (1) asperlicin C + H(+) + NADH + O2 = asperlicin E + H2O + NAD(+).
CA   (2) asperlicin C + H(+) + NADPH + O2 = asperlicin E + H2O + NADP(+).
CC   -!- The enzyme, characterized from the fungus Aspergillus alliaceus,
CC       contains an FAD cofactor.
CC   -!- The enzyme inserts a hydroxyl group, leading to formation of a
CC       N-C bond that creates an additional cycle between the bicyclic indole
CC       and the tetracyclic core moieties, resulting in the heptacyclic
CC       asperlicin E.
DR   P0DOW1, ASCM_PETAA ;
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