ID   1.14.13.216
DE   asperlicin C monooxygenase.
CA   (1) asperlicin C + NADH + O2 + H(+) = asperlicin E + NAD(+) + H2O.
CA   (2) asperlicin C + NADPH + O2 + H(+) = asperlicin E + NADP(+) + H2O.
CC   -!- The enzyme, characterized from the fungus Aspergillus alliaceus,
CC       contains an FAD cofactor.
CC   -!- The enzyme inserts a hydroxyl group, leading to formation of a
CC       N-C bond that creates an additional cycle between the bicyclic indole
CC       and the tetracyclic core moieties, resulting in the heptacyclic
CC       asperlicin E.
DR   P0DOW1, ASCM_PETAA ;
//