ID   1.14.13.22
DE   cyclohexanone monooxygenase.
AN   cyclohexanone:NADPH:oxygen oxidoreductase (6-hydroxylating, 1,2-
AN   lactonizing).
AN   cyclohexanone 1,2-monooxygenase.
AN   cyclohexanone oxygenase.
CA   cyclohexanone + H(+) + NADPH + O2 = H2O + hexano-6-lactone + NADP(+).
CC   -!- In the catalytic mechanism of this enzyme, the nucleophilic species
CC       that attacks the carbonyl group is a peroxyflavin intermediate that
CC       is generated by reaction of the enzyme-bound flavin cofactor with
CC       NAD(P)H and oxygen.
CC   -!- This enzyme is able to catalyze a wide range of oxidative reactions,
CC       including enantioselective Baeyer-Villiger reactions, sulfoxidations,
CC       amine oxidations and epoxidations.
DR   P12015, CHMO_ACISP ;
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