ID   1.14.13.222
DE   Aurachin C monooxygenase/isomerase.
AN   Aurachin C monooxygenase.
CA   Aurachin C + NAD(P)H + O(2) = 4-hydroxy-2-methyl-3-oxo-4-((2E,6E)-
CA   farnesyl)-3,4-dihydroquinoline-1-oxide + NAD(P)(+) + H(2)O.
CC   -!- The aurachin C monooxygenase from the bacterium Stigmatella
CC       aurantiaca accepts both NADH and NADPH as cofactor, but has a
CC       preference for NADH.
CC   -!- It catalyzes the initial steps in the conversion of aurachin C to
CC       aurachin B.
CC   -!- The FAD-dependent monooxygenase catalyzes the epoxidation of the
CC       C(2)-C(3) double bond of aurachin C, which is followed by a
CC       semipinacol rearrangement, causing migration of the farnesyl group
CC       from C(3) to C(4).
DR   H1ZZA4, AUAG_STIAU ;
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