ID   1.14.14.42
DE   homomethionine N-monooxygenase.
AN   CYP79F1.
CA   an L-polyhomomethionine + 2 reduced [NADPH--hemoprotein reductase] + 2 O2
CA   = an (E)-omega-(methylsulfanyl)-alkanal oxime + 2 oxidized [NADPH-
CA   -hemoprotein reductase] + CO2 + 3 H2O + 2 H(+).
CC   -!- Involved in methionine-derived aliphatic glucosinolates biosynthesis.
CC   -!- It catalyzes two successive N-hydroxylations, which are followed by
CC       dehydration and decarboxylation.
CC   -!- CYP79F1 from Arabidopsis thaliana can metabolize homo-, di-, tri-,
CC       tetra-, penta-, and hexahomomethionine to their corresponding
CC       aldoximes, while CYP79F2 from the same plant can only metabolize
CC       penta- and hexahomomethionine.
CC   -!- Formerly EC 1.14.13.n5.
DR   Q949U1, C79F1_ARATH;  Q9FUY7, C79F2_ARATH;
//