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ENZYME entry: EC 1.14.14.44

Accepted Name
Phenylacetaldehyde oxime monooxygenase.
Alternative Name(s)
CYP71AN24.
Reaction catalysed
(E)-phenylacetaldehyde oxime + [reduced NADPH--hemoprotein reductase] + O(2) <=> (R)-mandelonitrile + [oxidized NADPH--hemoprotein reductase] + 2 H(2)O
Cofactor(s)
Heme-thiolate.
Comment(s)
  • Involved in the biosynthesis of the cyanogenic glucosides (R)- prunasin and (R)-amygdalin.
  • It catalyzes three different activities - isomerization of the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation.
Cross-references
BRENDA1.14.14.44
EC2PDB1.14.14.44
ExplorEnz1.14.14.44
PRIAM enzyme-specific profiles1.14.14.44
KEGG Ligand Database for Enzyme Nomenclature1.14.14.44
IUBMB Enzyme Nomenclature1.14.14.44
IntEnz1.14.14.44
MEDLINEFind literature relating to 1.14.14.44
MetaCyc1.14.14.44
Rhea expert-curated reactions1.14.14.44
UniProtKB/Swiss-Prot
A0A068Q609, C7124_PRUMU

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