ID 1.14.14.77 DE phenylacetonitrile alpha-monooxygenase. AN CYP3201B1. CA O2 + phenylacetonitrile + reduced [NADPH--hemoprotein reductase] = (R)- CA mandelonitrile + H(+) + H2O + oxidized [NADPH--hemoprotein reductase]. CC -!- The enzyme has been characterized from the cyanogenic millipede CC Chamberlinius hualienensis. CC -!- Unlike plant enzymes that can catalyze this reaction (EC 1.14.14.44), CC this enzyme cannot act on phenylacetaldehyde oximes. CC -!- It can accept (4-hydroxyphenyl)acetonitrile, CC (2-methylphenyl)acetonitrile, and (3-methylphenyl)acetonitrile as CC substrates at a lower rate. DR A0A068Q609, C7124_PRUMU; //