ID 1.14.19.26 DE acyl-[acyl-carrier-protein] 6-desaturase. CA 2 H(+) + hexadecanoyl-[ACP] + O2 + 2 reduced [2Fe-2S]-[ferredoxin] = CA (6Z)-hexadecenoyl-[ACP] + 2 H2O + 2 oxidized [2Fe-2S]-[ferredoxin]. CC -!- The enzyme, characterized from the endosperm of the plant Thunbergia CC alata (black-eyed Susan vine), introduces a cis double bond at carbon CC 6 of several saturated acyl-[acyl-carrier protein]s. CC -!- It is most active with palmitoyl-[acyl-carrier protein] (16:0), CC but can also act on myristoyl-[acyl-carrier protein] (14:0) and CC stearoyl-[acyl-carrier protein] (18:0). CC -!- The position of the double bond is determined by its distance from CC the carboxyl end of the fatty acid. DR Q41510, PALAD_THUAT; //