ID   1.14.19.40
DE   hex-5-enoyl-[acyl-carrier protein] acetylenase.
CA   5-hexenoyl-[ACP] + 2 H(+) + O2 + 2 reduced [2Fe-2S]-[ferredoxin] =
CA   5-hexynoyl-[ACP] + 2 H2O + 2 oxidized [2Fe-2S]-[ferredoxin].
CC   -!- The enzyme, characterized from the marine cyanobacterium Moorea
CC       producens, is involved in production of the ion channel blocker
CC       jamaicamide A.
CC   -!- It is specific for hexanoate or hex-5-enoate loaded onto a dedicated
CC       acyl-carrier protein (JamC), which is encoded by a gene in the same
CC       operon.
DR   Q6E7K8, JAMB_MOOP1 ;
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