ID 1.14.19.75 DE very-long-chain acyl-lipid omega-9 desaturase. CA (1) a 1-hexacosanoyl-2-acyl-phosphoglycerolipid + 2 Fe(II)-[cytochrome CA b5] + 2 H(+) + O2 = a 1-[(17Z)-hexacos-17-enoyl]-2-acyl- CA phosphoglycerolipid + 2 Fe(III)-[cytochrome b5] + 2 H2O. CA (2) a 1-tetracosanoyl-2-acyl-phosphoglycerolipid + 2 Fe(II)-[cytochrome CA b5] + 2 H(+) + O2 = a 1-[(15Z)-tetracos-15-enoyl]-2-acyl- CA phosphoglycerolipid + 2 Fe(III)-[cytochrome b5] + 2 H2O. CC -!- The enzyme, characterized from the plant Arabidopsis thaliana, acts CC on both 24:0 and 26:0 fatty acids, introducing a cis double bond at a CC position 9 carbons from the methyl end. CC -!- These very-long-chain fatty acids are found as a minor component of CC seed lipids, but also in the membrane phosphatidylethanolamine and CC phosphatidylserine, in sphingolipids, as precursors and components of CC cuticular and epicuticular waxes, and in suberin. DR Q9SID2, ADS2_ARATH ; //