ID   1.14.19.81
DE   polyneuridine aldehyde synthase.
AN   CYP71AY4.
AN   CYP71AY5.
AN   sarpagan bridge enzyme.
CA   (19E)-geissoschizine + reduced [NADPH--hemoprotein reductase] + O2 =
CA   polyneuridine aldehyde + oxidized [NADPH--hemoprotein reductase] + 2 H2O
CA   + H(+).
CC   -!- A heme-thiolate protein (P450).
CC   -!- The enzyme, characterized from the plants Rauwolfia serpentina
CC       (Indian snakeroot) and Gelsemium sempervirens (yellow jessamine),
CC       is involved in the biosynthesis of monoterpenoid indole alkaloids of
CC       the sarpagan, ajmalan and alstophyllan classes.
DR   P0DO13, SBE1_RAUSE ;  P0DO14, SBE_GELSE  ;
//