ID   1.14.20.12
DE   3-[(E)-2-isocyanoethenyl]-1H-indole synthase.
CA   (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + 2-oxoglutarate + H(+) +
CA   O2 = 3-[(E)-2-isocyanovinyl]indole + 2 CO2 + H2O + succinate.
CC   -!- The enzyme has been characterized from an unidentified soil
CC       bacterium.
CC   -!- It catalyzes an Fe(2+), 2-oxoglutarate-dependent monooxygenation at
CC       C-3, which is followed by decarboxylation and dehydration, resulting
CC       in the generation of a trans C-C double bond. cf. EC 1.14.20.11.
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