ID   1.14.20.14
DE   hapalindole-type alkaloid chlorinase.
CA   (1) hapalindole U + chloride + 2-oxoglutarate + O2 + H(+) = hapalindole G
CA   + succinate + CO2 + H2O.
CA   (2) 12-epi-fischerindole U + chloride + 2-oxoglutarate + O2 + H(+) =
CA   12-epi-fischerindole G + succinate + CO2 + H2O.
CC   -!- The enzyme, characterized from hapalindole-type alkaloids-producing
CC       cyanobacteria, is a specialized iron(II)/2-oxoglutarate-dependent
CC       oxygenase that catalyzes the chlorination of its substrates in a
CC       reaction that requires oxygen, chloride ions, ferrous iron and
CC       2-oxoglutarate.
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