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ENZYME entry: EC 1.14.99.50

Accepted Name
Gamma-glutamyl hercynylcysteine S-oxide synthase.
Reaction catalysed
Hercynine + gamma-L-glutamyl-L-cysteine + O(2) <=> gamma-L-glutamyl-S-hercyn-2-yl-L-cysteine S-oxide + H(2)O
Cofactor(s)
Fe(2+).
Comment(s)
  • The enzyme, found in bacteria, is specific for both hercynine and gamma-L-glutamyl-L-cysteine.
  • It is part of the biosynthesis pathway of ergothioneine.
Cross-references
BRENDA1.14.99.50
EC2PDB1.14.99.50
ExplorEnz1.14.99.50
PRIAM enzyme-specific profiles1.14.99.50
KEGG Ligand Database for Enzyme Nomenclature1.14.99.50
IUBMB Enzyme Nomenclature1.14.99.50
IntEnz1.14.99.50
MEDLINEFind literature relating to 1.14.99.50
MetaCyc1.14.99.50
Rhea expert-curated reactions1.14.99.50
UniProtKB/Swiss-Prot
A0R5N0, EGTB_MYCS2;  G7CFI3, EGTB_MYCT3;  Q7D513, EGTB_MYCTO;  
O69671, EGTB_MYCTU;  

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