ID 1.21.98.3 DE anaerobic magnesium-protoporphyrin IX monomethyl ester cyclase. AN MPE cyclase. CA H2O + Mg-protoporphyrin IX 13-monomethyl ester + 3 S-adenosyl-L- CA methionine = 3,8-divinyl protochlorophyllide a + 3 5'-deoxyadenosine + CA 4 H(+) + 3 L-methionine. CC -!- This radical AdoMet enzyme participates in the biosynthesis of CC chlorophyllide a in anaerobic bacteria, catalyzing the formation of CC an isocyclic ring. CC -!- The same transformation is achieved in aerobic organisms by the CC oxygen-dependent EC 1.14.13.81. CC -!- Some facultative phototrophic bacteria, such as Rubrivivax CC gelatinosus, possess both enzymes. DR Q9RFD3, BCHE_CERS4 ; P26168, BCHE_RHOCB ; Q7X2C7, BCHE_RUBGE ; DR Q55373, BCHE_SYNY3 ; //