ID 1.3.1.100 DE chanoclavine-I aldehyde reductase. CA dihydrochanoclavine-I aldehyde + NADP(+) = chanoclavine-I aldehyde + CA H(+) + NADPH. CC -!- The enzyme participates in the biosynthesis of fumigaclavine C, CC an ergot alkaloid produced by some fungi of the Trichocomaceae CC family. CC -!- The enzyme catalyzes the reduction of chanoclavine-I aldehyde to CC dihydrochanoclavine-I aldehyde. CC -!- This hydrolyzes spontaneously to form 6,8-dimethyl-6,7- CC didehydroergoline, which is converted to festuclavine by EC 1.5.1.44. DR Q4WZ70, EASA_ASPFU ; W6Q9S9, FGOX3_PENRF; W6Q2D7, IFGG_PENRF ; //