ID 1.3.1.113 DE (4-alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate reductase. CA a [(3S,4R)-4-alkanoyl-5-oxooxolan-3-yl]methyl phosphate + NADP(+) = CA a (4-alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate + H(+) + CA NADPH. CC -!- The enzyme, characterized from the bacteria Streptomyces griseus and CC Streptomyces coelicolor, is involved in the biosynthesis of gamma- CC butyrolactone autoregulators that control secondary metabolism and CC morphological development in Streptomyces bacteria. DR B1VN94, BPRA_STRGG ; //