ID 1.3.1.120 DE cyclohexane-1-carbonyl-CoA reductase (NADP(+)). AN 1-cyclohexenylcarbonyl-CoA reductase. CA cyclohexane-1-carbonyl-CoA + NADP(+) = cyclohex-1-ene-1-carbonyl-CoA + CA H(+) + NADPH. CC -!- The enzyme, characterized from the bacterium Streptomyces collinus, CC is involved in a pathway that transforms shikimate to cyclohexane-1- CC carbonyl-CoA by a series of dehydration and double-bond reduction CC steps. CC -!- Most of the steps in this process occur with the carboxylic acid CC activated as a coenzyme A thioester. CC -!- The enzyme catalyzes three steps in this pathway, also acting on CC (3R,4R)-3,4-dihydroxy-3,4-dihydrobenzoyl-CoA and (5S)-5- CC hydroxycyclohex-1-ene-1-carbonyl-CoA. DR P95727, CHCA_STRCU ; //