ID   1.3.1.128
DE   precondylocarpine acetate reductase.
AN   dihydroprecondylocarpine acetate synthase.
CA   dihydroprecondylocarpine acetate + NADP(+) = precondylocarpine acetate +
CA   NADPH + H(+).
CC   -!- The enzyme, characterized from the plant Catharanthus roseus
CC       (Madagascar periwinkle), participates in a pathway that leads to the
CC       production of a number of monoterpene alkaloids, as well as the
CC       bisindole alkaloids vinblastine and vincristine, which are used as
CC       anticancer drugs.
CC   -!- The enzyme forms the iminium ion form of dihydroprecondylocarpine
CC       acetate, which spontaneously rearranges and undergoes deacylation,
CC       producing dehydrosecodine.
DR   A0A1B1FHP3, DPAS_CATRO ;
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