ID 2.3.1.190 DE acetoin dehydrogenase system. AN acetoin dehydrogenase. CA acetoin + CoA + NAD(+) = acetaldehyde + acetyl-CoA + H(+) + NADH. CC -!- Requires thiamine diphosphate. CC -!- It belongs to the 2-oxoacid dehydrogenase system family, which also CC includes EC 1.2.1.104, EC 1.2.1.105, EC 1.2.1.25 and EC 1.4.1.27. CC -!- With the exception of the glycine cleavage system, which contains 4 CC components, the 2-oxoacid dehydrogenase systems share a common CC structure, consisting of three main components, namely a 2-oxoacid CC dehydrogenase (E1), a dihydrolipoamide acyltransferase (E2), CC and dihydrolipoamide dehydrogenase (E3). //